Medium1 markMultiple Choice
Quantitative chemistryHighermolar ratiostoichiometryreacting masses

AQA GCSE · Question 07.3 · Quantitative chemistry

When iron reacts with chlorine, 0.12 mol of iron reacts with 0.18 mol of chlorine (Cl₂).
Which is the correct equation for the reaction?

Answer options:

A.

Fe + Cl₂ → FeCl₂

B.

Fe + 3Cl₂ → FeCl₆

C.

2Fe + Cl₂ → 2FeCl

D.

2Fe + 3Cl₂ → 2FeCl₃

How to approach this question

1. Find the simplest whole number ratio of the moles of reactants. 2. The ratio is 0.12 mol (Fe) : 0.18 mol (Cl₂). 3. To simplify, divide both numbers by the smallest value, which is 0.12. - Fe: 0.12 / 0.12 = 1 - Cl₂: 0.18 / 0.12 = 1.5 4. The ratio is 1 : 1.5. To get whole numbers, multiply both sides by 2. - 1 × 2 = 2 - 1.5 × 2 = 3 5. The simplest whole number ratio of Fe to Cl₂ is 2 : 3. 6. Look for the balanced equation that has a 2:3 ratio of Fe to Cl₂.

Full Answer

D.2Fe + 3Cl₂ → 2FeCl₃✓ Correct
To find the correct equation, we need to determine the molar ratio of the reactants from the experimental data. We are given: - Moles of iron (Fe) = 0.12 mol - Moles of chlorine (Cl₂) = 0.18 mol The ratio of moles is Fe : Cl₂ = 0.12 : 0.18. To simplify this ratio to the smallest whole numbers, we can divide both sides by the greatest common divisor, or simply divide by the smaller number and adjust. Divide both by 0.12: (0.12 / 0.12) : (0.18 / 0.12) 1 : 1.5 Ratios in chemical equations must be whole numbers, so we multiply the entire ratio by 2: (1 × 2) : (1.5 × 2) 2 : 3 This means that 2 moles of iron react with 3 moles of chlorine gas. We now look for the equation with this stoichiometric ratio. - A: Fe + Cl₂ (1:1 ratio) - B: Fe + 3Cl₂ (1:3 ratio) - C: 2Fe + Cl₂ (2:1 ratio) - D: 2Fe + 3Cl₂ (2:3 ratio) The correct equation is D.

Common mistakes

✗ Making a calculation error when simplifying the ratio. ✗ Choosing an equation that is not correctly balanced. ✗ Guessing without calculating the molar ratio.

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